Molecular motor powered by light alone

Chemists have developed the first molecular motor that can be powered by just light, irrespective of temperature.

Ludwig-Maximilians-Universitaetโ€™s Henry Dube and student Aaron Gerwien developed the motor, or chemical carousel, which even rotates faster at lower temperatures.

โ€œWe have succeeded in modifying the molecule such that a complete rotation of one of the structural modules relative to the other requires only three reaction steps,โ€ Dube said. โ€œEach rotation step is made up of three different photoreactions, two of which we experimentally demonstrated directly for the first time only this year.โ€

The new motor is based on an organic substance called hemithioindigo, made up of two different carbon skeletons, connected by a mobile double bond. The LMU team said all three steps involved in the full rotation are promoted by a reduction in temperature.

Dube and Gerwien believe their motorโ€™s driving mechanism will make it possible for researchers to synthesise molecular machines enabling new, unique applications.

Molecular motors, which rotate in a single direction in response to an external energy output, constitute an important class of components for future applications in nanotechnology. So far, light-driven molecular motors have been dependent on reactions that require heat and so rely on a minimum environmental temperature.

LMU had its findings published in the Journal of the American Chemical Society.

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